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http://hdl.handle.net/2282/385
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| Tittel: | PLS score-loading correspondence and a bi-orthogonal factorization |
| Forfattere: | Ergon, Rolf |
| Dato: | 2002 |
| Forlagets versjon: | http://dx.doi.org/10.1002/cem.736 |
| Sammendrag: | It is established industrial practice to use the correspondence between partial least squares (PLS)
scores and loadings or loading weights as a means for process monitoring and control. Deviations
from the normal operating point in a score plot are then related to the influences from major process
variables as shown in a loading or loading weight plot. These relations are often presented in a biplot,
i.e. appropriately scaled scores and loadings or loading weights are displayed in the same plot.
As shown in the present paper, however, the orthogonal PLS algorithm of Wold gives no direct
theoretical and graphical correspondence, i.e. the bi-plot will show an angle deviation that causes an
interpretational problem. The alternative non-orthogonal PLS algorithm of Martens gives direct
correspondence, but the correlated latent variables may then cause another interpretational problem.
As a solution to these problems, this paper presents a PLS factorization where both scores and
loadings are orthogonal (BPLS), and we show how the Wold and Martens factorizations can easily be
transformed to this solution. The result is independent latent variables as well as direct score and
loading correspondence. It is also shown that the transformations involved do not affect the
predictor found by PLS regression. The score-loading correspondence properties for the different
PLS factorizations are discussed using principal component analysis (PCA) as a reference case. An
example using industrial paper plant data is included. |
| Nøkkelord: | PLS
Factorization
Score-loading correspondence |
| Forlag: | Wiley |
| Dokumenttype: | Journal article |
| URI: | http://hdl.handle.net/2282/385 |
| Vises i samlingene: | Institutt for elektro, IT og kybernetikk
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